Azo Dyes from 4, 5-Disubstituted Imidazoles
نویسندگان
چکیده
منابع مشابه
Regioselective synthesis of 1,4-disubstituted imidazoles.
A short and efficient synthesis of 1,4-disubstituted imidazoles has been developed which provides the desired products with complete regioselectivity. This protocol allows preparation of compounds which are challenging to prepare by current literature methods in a regioselective fashion, a sterically and electronically diverse range of N-substituents being accessible. The sequence involves an u...
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New 1,2,4-triazole colorants were obtained, in high yields, by coupling 3-ethylthio-5-cyanomethyl-4-phenyl-1,2,4-triazole (1) with diazotized aniline derivatives 2, 4 and 6. The azo dyes prepared in this work may exist in three tautomeric forms. We found that the tautomerism is influenced mainly by the nature of substituent at the para position of the aniline coupling component. This tautomeris...
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The thiophene-based azo dyes class of azo dyes have generated considerable interest since its discovery 62 years ago. These dyes have come to be applied to a very large number and variety of fibres and have therefore achieved an importance which is probably greater than the weights used would suggest. The connection between dyeing and fastness properties on the one hand and chemical constitutio...
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Kinetics of anaerobic biodecolourisation (methanogenic environment) of four azo dyes (Acid Orange 6, Acid Orange 7, Methyl Orange and Methyl Red) was investigated with regard to their electrochemical properties as well as under variation of dye and sludge concentrations, pH and temperature. Cyclic voltammetry revealed a correlation between the potential of irreversible reduction peak of the dye...
متن کاملStructure and carcinogenic activity of azo dyes.
In recent years many investigations have been carried out on the carcinogenic activity of several groups of derivatives of 4-aminoazobenzene, their spectra, the relative basicities of their nitrogen atoms, and their metabolism (1, 2, 9, 14). The principal results on the correlation of structure and activity are as follows: Methylation.--3'-Methyl-4-dimethylaminoazobenzene is a tvery potent carc...
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ژورنال
عنوان ژورنال: The Journal of the Society of Chemical Industry, Japan
سال: 1970
ISSN: 0023-2734,2185-0860
DOI: 10.1246/nikkashi1898.73.10_2190